Hi Bravo,
Sounds like you have either cabbage worms aka imported cabbage worms, cabbage loopers or diamondback moth larvae.
http://www.urbanext.uiuc.edu/bugreview/cabbageworm.html
One of the best organic sprays is one with Bt aka Bacillus thuringiensis for these particular pests.* Javelin WG is a brand name for a spray.* From this site about halfway down the page.
http://www.ag.auburn.edu/aaes/commun...l97/sprays.htm
The active ingredient in Javelin WG is a toxin obtained from a bacterium, Bacillus thuringiensis variety kurstaki.
The toxin is active only against caterpillar pests, and acts as a stomach poison that must be consumed by the worms to be effective.
(The bold in the quote is mine.)
You can also use a ground red pepper spray or use another product called Align which contains Neem.* The problem with Neem is it targets beneficial insects as well.* You can make your own pepper spray.
http://www.ghorganics.com/page14.html#Pepper%20Spray
Garlic sray often works for these pests as well.* Here's how to make your own.
http://www.ghorganics.com/page14.htm...%20Oil%20Spray
You should find these recipes helpful.
http://www.ghorganics.com/page14.html
More helpful info on natural insect control.
http://www.ghorganics.com/page9.html
Enjoy your collards!
Newt
When weeding, the best way to make sure you are removing a weed and not a valuable plant is to pull on it. If it comes out of the ground easily, it is a valuable plant.